Відділ наноструктурних матеріалів імені Ю.В. Малюкіна (2315)
Основні напрямки діяльності
створення та фундаментальні дослідження фізико-хімічних властивостей багатофункціональних гібридних нанокомпозитів, редокс-активних нанокристалів, наноструктурних матеріалів на основі неорганічних нанокристалів простих та складних оксидів рідкісноземельних елементів та перехідних металів, в тому числі, сцинтиляційних нанокристалів, а також рідкокристалічних матриць, тощо, для широкого кола технічних та медико-біологічних застосувань.
Технологічне устаткування
testt
Завідувач відділу:
 Єфімова Світлана Леонідівна Член-кореспондент НАН України, доктор фізико-математичних наук, професор, т. +38 057 341-01-49 e-mail ephimova@isma.kharkiv.ua |
Співробітники відділу:
Основні проекти та публікації:
Dark Reactive Oxygen Species Generation in ReVO4:Eu3+ (Re = Gd, Y) Nanoparticles in Aqueous Solutions. Pavel O Maksimchuk, Svetlana L Yefimova, Kateryna O Hubenko, Valeriia V Omielaieva, Nataliya S Kavok, Vladimir K Klochkov, Olexander V Sorokin, Yuri V Malyukin. The Journal of Physical Chemistry – 2020. – V. 6. – p. 3843–3850.
X-ray Induced Hydroxyl Radical Generation by GdYVO4:Eu3+ Nanoparticles in Aqueous Solution: Main Mechanisms. Pavel O Maksimchuk, Svetlana L Yefimova, Valeriia V Omielaieva, Kateryna O Hubenko, Vladimir K Klochkov, Oleksandr D Opolonin, Yuri V Malyukin. Crystals – 2020. – V. 5. – p. 370–380.
Improving ˙OH scavenging properties of nanoceria by doping and pre-irradiation. V.V. Seminko, P.O. Maksimchuk, O.O. Sedyh, A.V. Aslanov, Yu.V. Malyukin.. Functional Materials – 2020. – V. 27. – p. 6–11.
Plasmon-Induced Suppression of Exciton Self-Trapping in Polymer-Bound Pseudoisocyanine J-Aggregates. Alexander V Sorokin, Irina I Grankina, Irina I Bespalova, Andrey V Aslanov, Svetlana L Yefimova, Yuri V Malyukin.. The Journal of Physical Chemistry C – 2020. – V. 124. – p. 10167–10174.
Light-triggered redox activity of GdYVO4:Eu3+ nanoparticles. S.L. Yefimova, P.O. Maksimchuk, K.O. Hubenko, V.V. Omielaieva, N.S. Kavok, V.K. Klochkov, Yu.V. Malyukin, V.P. Semynozhenko. Spectrochimica acta part a – 2020. – V. 242. – p. 118741.
Wavelength‐Selective Photoreduction of Colloidal CeO2−x Nanocrystals. V. Seminko, P. Maksimchuk, O. Avrunin, V. Semenets, Yu.V. Malyukin. Physica Status Solidi (b) – 2019.
Catalytic Decomposition of Hypochlorite Anions by Ceria Nanoparticles Visualized by Spectroscopic Techniques. V. Seminko, P. Maksimchuk, G. Grygorova, O. Avrunin, V. Semenets, V. K. Klochkov, Yu.V. Malyukin. The Journal of Physical Chemistry C. – 2019. – V. 123. – № 33. – p. 20675-20681.
Different Roles of Ce3+ Optical Centers in Oxyorthosilicate Nanocrystals at X-ray and UV Excitation. V. Seminko, P. Maksimchuk, I. Bespalova, Y. Malyukin. Crystals. – 2019. – V. 9. – № 2. – P. 114.
Janus-faced redox activity of LnVO4:Eu3+ (Ln = Gd, Y, La) nanoparticles. Svetlana L. Yefimova, Pavel O. Maksimchuk, Vladyslav Seminko, Nataliya S. Kavok, Vladimir K. Klochkov, Kateryna A. Hubenko, Alexander V. Sorokin, Irina Yu. Kurilchenko, Yuri V. Malyukin. The Journal of Physical Chemistry C. – 2019. – № 123. – p. 15323-15329.
Untangling the Mechanisms of GdYVO4:Eu3+ nanoparticle Photocatalytic Activity. S.L. Yefimova, P.O. Maksimchuk, K.A. Hubenko, V.K. Klochkov, A.V. Sorokin, Yu.V. Malyukin. Colloids and Surfaces A. – 2019. – № 577. – p. 630-636.
Unusual enhancement of dye luminescence by exciton resonance of J-Aggregates. Alexander V Sorokin, Iryna Yu Ropakova, Irina I Grankina, Igor A Borovoy, Svetlana L Yefimova, Yuri V Malyukin. Optical Materials – 2019. – V.96. – P. 109263.
Exciton Dynamics and Self-Trapping of Carbocyanine J-Aggregates in Polymer Films. Alexander V Sorokin, Irina Yu Ropakova, Steffen Wolter, Regina Lange, Ingo Barke, Sylvia Speller, Svetlana L Yefimova, Yuri V Malyukin, Stefan Lochbrunner. The Journal of Physical Chemistry C. – 2019. – V. 123. – № 14. – p. 9428-9444
Adsorption of ions on model phospholipid membranes. O.V. Vashchenko, N.A. Kasian, L.V. Budianska, R.Ye. Brodskii, I.I. Bespalova, L.N. Lisetski. Journal of Molecular Liquids. – 2019. – V. 275. – p. 173-177.
Reactive oxygen species generation in aqueous solutions containing GdVO4:Eu3+ nanoparticles and their complexes with methylene blue. K. Hubenko, S. Yefimova, T. Tkacheva, P. Maksimchuk, I. Borovoy, V. Klochkov, N. Kavok, O. Opolonin, Yu. Malyukin. Nanoscale research letters. – 2018. – Vol. 13. – №. 1. – P. 100.
Hydrogen peroxide sensing using Ce3+ luminescence of cerium oxide (CeO2-x) nanoparticles. Yu. Malyukin, V. Seminko, P. Maksimchuk, E. Okrushko, O. Sedyh, Yu. Zorenko. Optical Materials. – 2018. – Vol. 85. – P. 303-307.
Molecular Arrangement in Cyanine Dye J-Aggregates Formed on CeO2 Nanoparticles. S.L. Yefimova, G.V. Grygorova, V.K. Klochkov, I.A. Borovoy, A.V Sorokin, Yu.V. Malyukin. The Journal of Physical Chemistry C. – 2018. – Vol. 122. – №. 36. – P. 20996-21003.
Excimer Emission of Acridine Orange Adsorbed on Gadolinium-Yttrium Orthovanadate Nanoparticles. K.O. Hubenko, S.L. Yefimova, T.N. Tkacheva, P.O. Maksimchuk, O.O. Sedyh, O.G. Viagin, A.V. Sorokin, Yu.V. Malyukin. Journal of fluorescence. – 2018. – Vol. 28. – №. 4. – P. 943-949.
Limitations of Self-Regenerative Antioxidant Ability of Nanoceria Imposed by Oxygen Diffusion. Yu. Malyukin, P. Maksimchuk, V. Seminko, E. Okrushko, N. Spivak. The Journal of Physical Chemistry C. – 2018. – Vol. 122. – №.28. – P. 16406–16411.
Oxidation-reduction processes in CeO2-x nanocrystals under UV irradiation. V.K. Klochkov, Yu.V. Malyukin, G.V. Grygorova, O.O. Sedyh, N.S. Kavok, V.V. Seminko, V.P. Semynozhenko. Journal of Photochemistry and Photobiology A: Chemistry. – 2018. - Vol. 364. – P. 282-287.
Porous CaCO3 carriers loaded with scintillation nanoparticles and photosensitizer molecules for photodynamic activation. S.L. Yefimova, T.N. Tkacheva, P.O. Maksimchuk, I.I. Bespalova, K.O. Hubenko, I.A. Borovoy, G.V. Grygorova, V.P. Semynozhenko, R.S. Grynyov, A.V. Sorokin, Yu.V Malyukin. Microporous and Mesoporous Materials. – 2018. – Vol. 263. – P. 128-134.
Strong Difference between Optical Properties and Morphologies for J-Aggregates of Similar Cyanine Dyes. A.V. Sorokin, I.Yu. Ropakova, R.S. Grynyov, M.M. Vilkisky, V.M. Liakh, I.A. Borovoy, S.L. Yefimova, Yu.V. Malyukin. Dyes and Pigments. – 2018. – Vol. 152. – P. 49–53.
Insight into the mechanism of the photoluminescence of carbon nanoparticles derived from cryogenic studies. Yu. Malyukin, O. Viagin, P. Maksimchuk, M. Dekaliuk, A. Demchenko. Nanoscale. – 2018. – Vol. 10. – №. 19. – P . 9320-9328.
Anomalous optical properties of photoactive cholesteric liquid crystal doped with single-walled carbon nanotubes. A.N. Samoilov, S.S. Minenko, L.N. Lisetski, M.S. Soskin, S.I. Torgova, N.I. Lebovka. Liquid Crystals. – 2018. – Vol. 45, – №.2, – P.250-261.
Study of the Combined Effect of Ibuprofen and Cholesterol on the Microviscosity and Ordering of Model Lipid Membranes by Timeresolved Measurement of Fluorescence Anisotropy Decay. S.L. Yefimova, T.N. Tkacheva, N.A. Kasian. J. Appl. Spectrosc. – 2017. – V. 84. – P. 284–290.
GdVO4:Eu3+ nanoparticles – Methylene Blue complexes for PDT: Electronic excitation energy transfer study. S.L. Yefimova, T.N. Tkacheva, P.O. Maksimchuk, I.I. Bespalova, K.O. Hubenko, V.K. Klochkov, A.V. Sorokin, Yu.V. Malyukin. Journal of Luminescence. – 2017. – V. 192. – P. 975–981.
The role of serum proteins in the stabilization of colloidal LnVO4:Eu3+ (Ln = La, Gd, Y) and CeO2 nanoparticles. N. Kavok, G. Grygorova, V. Klochkov, S. Yefimova. Colloids and Surfaces A. – 2017. – V. 529. – P. 594–599
Oscillations of Cerium Oxidation State Driven by Oxygen Diffusion in Colloidal Nanoceria (CeO2−x). Yu.Malyukin, V. Klochkov, P. Maksimchuk, V. Seminko, N. Spivak. Nanoscale Research Letters – 2017. – V. 12:566.
ZnSe nanocrystals obtained in pores of SiO2 matrix with temperature stable green luminescence. A.A. Masalov, V.V. Seminko, N.V. Kononets, P.O. Maksimchuk, I.I. Bespalova, Yu.V. Malyukin. Journal of Luminescence. – 2017. – V. 181. – P. 337–344.
Defect and intrinsic luminescence of CeO2 nanocrystals. V. Seminko, P. Maksimchuk, I. Bespalova, A. Masalov, O. Viagin, E. Okrushko, N. Kononets, Yu. Malyukin. Physica Status Solidi (b). – 2017. – V. 254.
Processes of energy migration in mixed europium–lanthanum magnesium borate nanocrystals. N.V. Kononets, V.V. Seminko, P.O. Maksimchuk, I.I. Bespalova, A.A. Masalov, Y.V. Malyukin, B.V. Grinyov. Spectroscopy Letters. – 2017. – V. 50. – P. 399–403.
Optical density and microstructure-related properties of photoactive nematic and cholesteric liquid crystal colloids with carbon nanotubes. L.N. Lisetski, S.S. Minenko, A.S. Samoilov, N.I. Lebovka. J. Mol. Liq.– 2017. – V. 235. – P. 90–97.
Anomalous optical properties of photoactive cholesteric liquid crystal doped with single-walled carbon nanotubes. A.N. Samoilov, S.S. Minenko, L.N. Lisetski, M.S. Soskin, S.I. Torgova, N.I.Lebovka. Liq.Cryst. – 2017.
The characteristics of interaction of pharmaceuticals and their active ingredients with lipid membranes. A.O. Sadchenko, O.V. Vashchenko, A.Yu. Pugovkin, E.F. Kopeika, N.A. Kasian, L.V. Budianska, A.V. Mashchenko, Ya.M. Al-Mugkhrabi, D.S. Sofronov, L.N. Lisetski. Biophysics. – 2017. – V. 62, No.4. – P. 570–579.
Configuration of Organic Dye Excimers in Nanoporous SiO2 Matrices. A.V. Sorokin, B.A. Gnap, I.I. Bespalova, S.L. Yefimova, Yu.V. Malyukin. J. Lumin. – 2016. – v. 179. – P. 171–177.
Synthesis and characterization of mesoporous CaCO3@PSS microspheres as a depot system for sustained Methylene Blue delivering. S.L. Yefimova, I.I. Bespalova, G.V. Grygorova, A.V. Sorokin, P.V. Mateychenko, X.Q. Cui, Yu. V. Malyukin. Microporous and Mesoporous Materials. – 2016. – v. 236. – P. 120–128.
Cerium Dioxide CeO2-x and Orthovanadate (Gd0.9Eu0.1VO4) Nanoparticles for Protection of Living Body from X-Ray Induced Damage. G. Grygorova, V. K. Klochkov, Ye. Mamotyuk, Yu.V. Malyukin. In book: Nanomaterials for Security, Springer. 2016.P.289-296
Spectroscopic Properties of Nanoceria Allowing Visualization of Its Antioxidant Action. V. Seminko, A. Masalov, P. Maksimchuk, V. K. Klochkov, I. Bespalova, O. Viagin, Yu. V. Malyukin. In book: Nanomaterials for Security, Springer. 2016. P.149-157.
Spectroscopic properties of nanoceria allowing visualization of its antioxidant action. V. Seminko, A. Masalov, P. Maksimchuk, V. Klochkov, I. Bespalova, O. Viagin, and Yu. Malyukin. Nanomaterials for Security. – 2016. – P. 149-157.
Luminescent properties of composite scintillators based on PPO and o-POPOP doped SiO2 xerogel matrices. O. Viagin, A. Masalov, I. Bespalova, O. Zelenskaya, V. Tarasov, V.Seminko, L. Voloshina, Yu. Malyukin, Yu. Zorenko. Journal of Luminescence. – 2016. – V. 179. – P. 178-182.
Plasmon controlled exciton fluorescence of molecular aggregates / A.V. Sorokin, A.A. Zabolotskii, N.V. Pereverzev, S.L. Yefimova, Yu.V. Malyukin, A.I. Plekhanov // J.Phys.Chem.C. – 2014. – v. 118, №14. – P. 7599-7605
Spectroscopic Study of Interactions between Dye Molecules in Micelle and Liposome Nanovolumes / S.L. Yefimova, T. N. Tkacheva, I. Yu. Kurilchenko, A. V. Sorokin, and Yu. V. Malyukin // J. Appl. Spectr. – 2013. – v. 79, № 6. – P. 914-921
Exciton transport in amphi-PIC J-aggregates formed in polymer films / A.V. Sorokin, I.I. Fylymonova, S.L. Yefimova, Yu.V. Malyukin // Opt. Mater. – 2012. – v. 32, № 12. – P. 2091-2094.
Control of electron-lattice interaction in organic nanoclusters / Yu.V. Malyukin, B.A. Gnap, A.V. Sorokin, S.L. Yefimova // Opt. Mater. – 2012. – v. 32, № 12. – P. 2008-2011.
Comparative study of dye-loaded liposome accumulation in sensitive and resistant human breast cancer cells / S.L. Yefimova, I.Yu. Kurilchenko, T.N. Tkacheva, V.A. Rozhkov, A.V. Sorokin, N.Yu. Lukianova, N.А. Bezdenezhnykh, Yu.V. Malyukin, V.F. Chekhun // Exp. Oncol. – 2012. – v. 34, № 2. – P. 101–106.
J-type aggregation of squaraine dye Sq-2Me in surfactant solutions / S. Yefimova, A. Lebed, A. Sorokin, G. Guralchuk, I. Borovoy, Yu. Malyukin // J. of Molecular Liquids. – 2012. – v. 165. – P. 113–118.
Nano-scale liposomal container with a «signal system» for substances delivering in living cells / S.L. Yefimova, A.S. Lebed, G.Ya. Guralchuk, A.V. Sorokin, I.Yu. Kurilchenko, N.S. Kavok , Yu.V. Malyukin // Biopolymers and Cell. – 2011. – Vol. 27, № 1. – P. 47–52.
Influence of Dye Hydrophobicity on the Efficiency of Fluorescence Resonance Energy Transfer Between Dyes in Surfactant Micelles / S.L. Yefimova, A.S. Lebed, G.Ya. Guralchuk, A.V. Sorokin, and Yu.V. Malyukin // Mol. Cryst. Liq. Cryst. – 2011. – v. 535. – P. 204-211.
Manifestation of Exciton-Lattice Interaction in J-aggregates / I.K. Katrunov, A.V. Sorokin, S.L. Yefimova, Yu.V. Malyukin // Mol. Cryst. Liq. Cryst. – 2011. – v. 535. – P. 57-63.
Excitation localization effects in nanoscale molecular clusters (J-aggregates) / S. L. Yefimova, A. V. Sorokin, I. K. Katrunov, and Yu. V. Malyukin // Low Temp. Phys. – 2011. – v. 37, № 2. – P. 157-162.
Effect of hydrophobicity of cationic carbocyanine dyes DiOCn on their binding to anionic surfactant micelles / A. S. Lebed, S. L. Yefimova, G. Ya. Guralchuk, A. V. Sorokin, I. A. Borovoy and Yu. V. Malyukin // J. Appl. Spectrosc. – 2010. – v. 77, № 2. – P. 183-188.
Control of Exciton Migration Efficiency in Disordered J-Aggregates / A.V. Sorokin, I.I. Filimonova, R.S. Grynyov, G.Ya. Guralchuk, S.L. Yefimova, Yu.V. Malyukin // J. Phys. Chem. C. – 2010. – v. 114, № 2. – P. 1299-1305.
Coherent Mechanism of Exciton Transport in Disordered J-Aggregates / A.N. Lebedenko, R.S. Grynyov, G.Ya. Guralchuk, A.V. Sorokin, S.L. Yefimova, Y.V. Malyukin // J. Phys. Chem. C. – 2009 – v. 113, № 29. – P. 12883–12887.
Control of Optical Properties of Polymethine Dye J-Aggregates Using Different Additives / A. V. Sorokin / J. Appl. Spectroscopy – 2009. – v. 76, № 2. – P. 234-239.
Squaraine dye as an exciton trap for cyanine J-aggregates in a solution / R.S. Grynyov, A.V. Sorokin, G.Ya. Guralchuk, S.L. Yefimova, I.A. Borovoy, Yu.V. Malyukin // J. Phys. Chem. C. – 2008. – v.112, № 51. – P. 20458–20462.
Hydrophobicity effect on interactions between organic molecules in nanocages of surfactant micelle / S.L. Yefimova, G.Ya. Gural’chuk, A.V. Sorokin, Yu.V. Malyukin, I.A. Borovoy and A.S. Lubyanaya // J. Appl. Spectrosc., – 2008. – v.75, № 5. – P. 658-663.
Anomalous surfactant-induced enhancement of luminescence quantum yield of cyanine dye J-aggregates / G.Ya. Guralchuk, I.K. Katrunov, R.S. Grynyov, A.V. Sorokin, S.L. Yefimova, I.A. Borovoy, Yu.V. Malyukin // J. Phys. Chem. C. – 2008. – v.112, № 38. – P. 14762-14768.
Specificity of cyanine dye L-21 aggregation in solutions with nucleic acids / G.Ya. Guralchuk, A.V. Sorokin, I.K. Katrunov, S.L. Yefimova, A.N. Lebedenko, Yu.V. Malyukin, S.M. Yarmoluk // J. Fluorescence – 2007. – v.17, № 4. – P. 370-376.
Pseudoisocyanine J-Aggregate to Optical Waveguiding Crystallite Transition: Microscopic and Microspectroscopic Exploration / Alexander N. Lebedenko, Gleb Ya. Guralchuk, Alexander V. Sorokin, Svetlana L. Yefimova, and Yuri V. Malyukin // J. Phys. Chem. B. – 2006. – v.110, № 36. – P. 17772-17775.
Nonradiative excitation energy transfer in carbocyanine dye compositions inside surfactant micelles / S.L. Efimova, А.V. Sorokin, А.N. Lebedenko, Yu.V. Malyukin, О.N. Obukhova // J. Appl. Spectrosc. – 2006. – v.73, № 2. – P.164-170
Optical Spectroscopy on Individual amphi-PIC J-aggregates / Erwin Lang, Alexander Sorokin, Markus Drechsler, Yuri V. Malyukin and Jürgen Köhler // Nano Letters. –2005. – v.5, №12. – P.2635-2640.
Co-existence of free and self-trapped excitons in J-aggregates / Yu.V. Malyukin, A.N. Lebedenko, A.V. Sorokin and S.L. Efimova // Journal of Luminescence.– 2005.– v.112.– P.424-428.
Nano-scale control of energy transfer in the system “donor-acceptor” / S.L. Efimova, Yu.V. Malyukin, A.V. Sorokin, A.N. Lebedenko and I.A.Borovoy // Journal of Luminescence.– 2005.– v.112.– P.439-443.
Photo-induced reorganization of molecular packing of amphi-PIC J-aggregates (Single J-aggregate spectroscopy) / Yu.V. Malyukin, A.V. Sorokin, S.L. Efimova and A.N. Lebedenko // Journal of Luminescence.– 2005.– v.112.– P.429-433.
Features of low-temperature exciton dynamics in J-aggregates with topological disorder / Yu.V. Malyukin, G.S. Katrich, S.L. Efimova, and A.V. Sorokin // Low Temp. Phys. – 2003. – v.29, № 8.– P.679-681.
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